VK Jaiswal Inorganic Chemistry JEE

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    VK Jaiswal Inorganic Chemistry JEE Objective for Students

    Quick Quiz

    Which of the following is not correct about carbon monoxide?

    (A) It is produced due to incomplete combustion

    (B) It forms carboxyhemoglobin

    (C) It reduces the oxygen-carrying ability of blood

    (D) The carboxyhemoglobin (hemoglobin bound to CO) is less stable than oxyhemoglobin.

    Option d – The carboxyhemoglobin (hemoglobin bound to CO) is less stable than oxyhemoglobin

    Which one of the following has the maximum number of atoms?

    (A) 1g of Li(s) [Atomic mass of Li = 7]

    (B) 1g of Ag(s) [Atomic mass of Ag = 108]

    (C) 1g of Mg(s) [Atomic mass of Mg = 24]

    (D) 1g of O2(g) [Atomic mass of O = 16]

    Option a – 1g of Li(s) [Atomic mass of Li = 7]

    Which of the following is a basic amino acid?

    (A) Lysine

    (B) Serine

    (C) Alanine

    (D) Tyrosine

    Option a – Lysine

    The following metal ion activates many enzymes, participates in the oxidation of glucose to produce ATP, and with Na, is responsible for the transmission of nerve signals.

    (A) Potassium

    (B) Iron

    (C) Copper

    (D) Calcium

    Option a – Potassium

    Measuring Zeta potential is useful in determining which property of a colloidal solution.

    (A) Size of the colloidal particles

    (B) Viscosity

    (C) Solubility

    (D) Stability of the colloidal particles

    Option d – Stability of the colloidal particles

    An increase in the concentration of the reactants of a reaction leads to a change in:

    (A) collision frequency

    (B) activation energy

    (C) heat of reaction

    (D) threshold energy

    Option a – collision frequency

    The synthesis of alkyl fluorides is best accomplished by:

    (A) Finkelstein reaction

    (B) Swart’s reaction

    (C) Sandmeyer’s reaction

    (D) Free radical fluorination

    Option b – Swart’s reaction

    Which of the following is not formed when a mixture of methyl bromide and bromobenzene is heated with sodium metal in the presence of dry ether?

    (A) Ethane

    (B) Propane

    (C) Toluene

    (D) Diphenyl

    Option b – Propane

    Electrons in the valence shell of the carbanion are:

    (A) 6

    (B) 10

    (C) 8

    (D) 5

    Option c – 8

    How many chiral stereoisomers can be drawn for 2-Bromo-3-chlorobutane?

    (A) 2

    (B) 3

    (C) 4

    (D) 5

    Option c – 4

    The major product of the reaction between ter butyl chloride and sodium ethoxide is:

    (A) 2-Methyl prop-1-ene

    (B) 1-Butene

    (C) 2-Butene

    (D) n-Butyl chloride

    Option a – 2-Methyl prop-1-ene

    Which of the following reactions will not result in the formation of carbon-carbon bonds?

    (A) Friedel-Crafts acylation

    (B) Reimer-Tieman reaction

    (C) Cannizaro reaction

    (D) Wurtz reaction

    Option c – Cannizaro reaction

    When glycerol is treated with excess of HI, it produces:

    (A) Allyl iodide

    (B) Propene

    (C) Glycerol triiodide

    (D) 2-iodopropane

    Option d – 2-iodopropane

    The heating of phenyl-methyl ethers with HI produces:

    (A) Iodobenzene

    (B) Phenol

    (C) Benzene

    (D) Ethyl chlorides

    Option b – Phenol

    The best reagent to convert pent-3-en-2-ol into pent-3-in-2-one is:

    (A) Acidic dichromate

    (B) Acidic permanganate

    (C) Pyridinium chloro-chromate

    (D) Chromic anhydride in glacial acetic acid

    Option d – Chromic anhydride in glacial acetic acid

    Phenyl magnesium bromide reacts with methanol to give:

    (A) A mixture of benzene and Mg(OMe)Br

    (B) A mixture of toluene and Mg(OH)Br

    (C) A mixture of phenol and Mg(Me)Br

    (D) A mixture of anisole and Mg(OH)Br

    Option a – A mixture of benzene and Mg(OMe)Br

    Ethyl alcohol is less acidic than phenol because:

    (A) The phenoxide ion is more resonance stabilized than phenol

    (B) There is more hydrogen bonding in phenol than in ethyl alcohol

    (C) The ethoxide ion is less resonance stabilized than ethyl alcohol

    (D) Phenol has a higher b.p. than ethyl alcohol

    Option a – The phenoxide ion is more resonance stabilized than phenol

    Which of the following pairs can be distinguished by iodine and dilute NaOH:

    (A) N-propyl alcohol and n-butyl alcohol

    (B) t-Butyl alcohol and s-butyl alcohol

    (C) Benzyl alcohol and cyclohexanol

    (D) n-Propyl alcohol and ethyl methyl ether

    Option b – t-Butyl alcohol and s-butyl alcohol

    The order of reactivity of methyl alcohol (I), isopropyl alcohol (II) tertiary butyl alcohol (III), and ethyl alcohol (IV) for esterification in decreasing order will be:

    (A) I > II > III > IV

    (B) IV > III > II > I

    (C) I > IV > II > III

    (D) I > IV > III > II

    Option c – I > IV > II > III

    The reactivity of alcohols with HCl is in the order of:

    (A) Tert butyl alcohol > sec. butyl alcohol > primary butyl alcohol

    (B) Primary butyl alcohol > sec. butyl alcohol > tert butyl alcohol

    (C) Sec. butyl alcohol > tert butyl alcohol > primary butyl alcohol

    (D) Sec. butyl alcohol > primary butyl alcohol > tert butyl alcohol

    Option a – Tert butyl alcohol > sec. butyl alcohol > primary butyl alcohol

    The correct order of boiling points of n-pentane, butyraldehyde, diethyl ether and n-butyl alcohol is:

    (A) n-Pentane > butyraldehyde > diethyl ether > n-butyl alcohol

    (B) n-Pentane > diethyl ether > butyraldehyde > n-butyl alcohol

    (C) n-Butyl alcohol > butyraldehyde > n-pentane > diethyl ether

    (D) n-Butyl alcohol > diethyl ether > n-pentane > butyraldehyde

    Option c – n-Butyl alcohol > butyraldehyde > n-pentane > diethyl ether

    Methylethylketone can be obtained by the oxidation of:

    (A) 2-Butanol

    (B) 2-Propanol

    (C) 1-Butanol

    (D) Tert.butyl alcohol

    Option a – 2-Butanol

    Which of the following is the odd one out?

    (A) Potassium ferrocyanide

    (B) Ferrous ammonium sulfate

    (C) Potassium ferricyanide

    (D) Tetrammine copper (II) sulfate

    Option b – Ferrous ammonium sulfate

    When 0.1 mol, CoCl3 (NH3)5 is treated with an excess of AgNO3, 0.2 mol of AgCl are obtained the conductivity of the solution will correspond to :

    (A) 1.3 electrolyte

    (B) 1.2 electrolyte

    (C) 1.1 electrolyte

    (D) 3.1 electrolyte

    Option b – 1.2 electrolyte

    A Chelating agent has two or more two donor atoms to bind to a single metal ion. Which of the following is not a chelating agent?

    (A) Thiosulhate

    (B) Oxalato

    (C) Glycinato

    (D) Ethane-1,2-diamine

    Option a – Thiosulhate

    According to Lewis’s theory, ligands are

    (A) Acidic in nature

    (B) Basic in nature

    (C) Neither acidic nor basic

    (D) Some are acidic some are basic

    Option b – Basic in nature

    The coordination number of central metal atoms in a complex is determined by

    (A) The number of ligands around the metal bonded by sigma and Pi bonds

    (B) The number around the metal ion bonded! by Pi- bonds

    (C) The number of ligands around a metal ion bonded by sigma bonds

    (D) The number of only anionic ligands

    Option c – The number of ligands around a metal ion bonded by sigma bonds

    In the extraction of which of the following a complex ion is formed?

    (A) Cu

    (B) Ag

    (C) Fe

    (D) Na

    Option b – Ag

    Potassium ferrocyanide is an

    (A) Normal salt

    (B) Double salt

    (C) Mixed salt

    (D) Complex salt

    Option d – Complex salt

    The ion or molecule which forms a complex compound with a transition metal ion is called

    (A) Recipient

    (B) Ligand

    (C) Coordinate ion

    (D) Cation

    Option b – Ligand

    The primary valency of cobalt in CoCl3.6NH3, CoCl3.5NH3, and CoCl3.4NH3 is respectively

    (A) 6, 5, 4

    (B) 3, 2, 1

    (C) 0, 1, 2

    (D) 3, 3, 3

    Option b – 3, 2, 1

    Which is not a colligative property?

    (A) Lowering in B.P.

    (B) Osmotic pressure

    (C) Elevation in B.P.

    (D) Freezing point

    Option d – Freezing point

    The osmotic pressure of a 0.6% (w/v) solution of urea is 300 mm at 298 K. The osmotic pressure of a 0.2 M cane sugar solution at the same temperature is

    (A) 150 mm

    (B) 600 mm

    (C) 30 mm

    (D) 300 mm

    Option a – 150 mm

    The vapour pressure of the sucrose solution decreased by the addition of 68.4 of sucrose in 100 g pure water (V.P. of pure solvent is 23.8 mm Hg)

    (A) 22.943 mm

    (B) 23.948 mm

    (C) 20.943 mm

    (D) 21.948 mm

    Option a – 22.943 mm

    During osmosis, the flow of solvent through the semipermeable membrane is from

    (A) Solution of higher concentration only

    (B) Both solution and solvent side with equal rate.

    (C) Both sides through a membrane with an unequal rate

    (D) Solution of lower concentration only.

    Option d – Solution of lower concentration only

    5.25% of the substance solution is isotonic with 1.5% urea solution in the same solvent. The molar mass of a substance

    (A) 90 g

    (B) 115 g

    (C) 210 g

    (D) 105 g

    Option c – 210 g

    Colligative properties are used for the determination of

    (A) Molar mass

    (B) Equivalent mass

    (C) M. P. and B.P.

    (D) Arrangement of molecules

    Option a – Molar mass

    0.5 g of nonvolatile solute with a molar mass of 65 is dissolved in 500 ml of CCl4. The vapour pressure of the solution is (V.P. of CCl4 is 143 mm at 25°C, d = 1.58 g/cm³)

    (A) 141.93 mm

    (B) 99.39 mm

    (C) 199.34 mm

    (D) 143.99 mm

    Option a – 141.93 mm

    The vapour pressure of water at 20°C is 17.5 mm. If 18 g of glucose dissolved in 178.2 g of water. The vapour pressure of the solution becomes

    (A) 16.500 mm

    (B) 15.750 mm

    (C) 16.675 mm

    (D) 17.325 mm

    Option d – 17.325 mm

    A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of 290 mm at 27°C. The V.P. of propyl alcohol is 200 mm. If the mole fraction of ethyl alcohol is 0.60. Its vapour pressure at the same temperature is

    (A) 350 mm

    (B) 360 mm

    (C) 700 mm

    (D) 300 mm

    Option a – 350 mm

    The maximum vapour pressure at 27°C is for

    (A) 1 M sugar

    (B) 1 M acetic acid

    (C) 1 M CaCl₂

    (D) 1 M NaCl

    Option a – 1 M sugar

    Addition of a non-volatile solute in the solvent, the vapour pressure of the solvent decreases from 50 mm to 45 mm at 303 K. The mole fraction of solute is

    (A) 0.010

    (B) 0.100

    (C) 0.005

    (D) 0.900

    Option b – 0.100

    The vapour pressure of pentane and hexane are 440 mm and 120 mm respectively. If their mole ratio is 1 : 4. The mole fraction of pentane in the vapour phase is

    (A) 0.549

    (B) 0.478

    (C) 0.787

    (D) 0.200

    Option b – 0.478

    Approximately, how many different chemical elements exist on the Earth?

    (A) 300

    (B) 250

    (C) 200

    (D) 100

    Option d – 100

    Which of the following is a fundamental element?

    (A) Sand

    (B) Diamond

    (C) Marble

    (D) Sugar

    Option b – Diamond

    The chemical composition of a diamond is

    (A) Carbon

    (B) Nitrogen

    (C) Nickel

    (D) Zinc

    Option a – Carbon

    Assertion (A): In the periodic table of chemical elements, electron affinity is always found to increase from top to bottom in a group. Reason (R): In a group, the atomic radii generally increase from top to bottom.

    (A) Both (A) and (R) are true and (R) is the correct explanation of (A)

    (B) Both (A) and (R) are true, but (R) is not the correct explanation of (A)

    (C) (A) is true, but (R) is false

    (D) (A) is false, but (R) is true

    Option d – (A) is false, but (R) is true

    Consider the following statements with reference to the periodic table of chemical elements. 1. Ionization potential gradually decreases over a period. 2. In a group of elements, electron affinity decreases as the atomic weight increases. In a given period, electronegativity decreases as the atomic number increases. Which of these statement(s) is/are correct?

    (A) Only 1

    (B) Only 2

    (C) Only 1 and 3

    (D) Only 2 and 3

    Option b – Only 2

    What is the usual property of oxides of Group III and IV?

    (A) Basic and acidic

    (B) Basic

    (C) Acidic

    (D) Neutral

    Option a – Basic and acidic

    The element found maximum in the soil layer is

    (A) Oxygen

    (B) Nitrogen

    (C) Manganese

    (D) Silicon

    Option a – Oxygen

    Which one of the following is present in the largest amount in terms of percent by mass in the Earth’s crust?

    (A) Silicon

    (B) Oxygen

    (C) Carbon

    (D) Calcium

    Option b – Oxygen

    Which is the most abundant element after oxygen?

    (A) Silicon

    (B) Carbon

    (C) Sodium

    (D) Chlorine

    Option a – Silicon

    Which of the following is the most common element in the Universe?

    (A) Hydrogen

    (B) Oxygen

    (C) Nitrogen

    (D) Carbon

    Option a – Hydrogen

    Temperature to which simple pottery is subjected to :

    1. 1100°C

    2. 1450 1800°C

    3. 600 – 900°C

    4. 150-600°C

    Option 1 – 1100°C

    Terracotta articles are

    1. Glazed

    2. Porous

    3. Hard

    4. Soft

    Option 2 – Porous

    Simple pottery ware made from

    1. Common clay

    2. Red clay

    3. Black clay

    4. None of these

    Option 1 – Common clay

    Give an example for simple pottery articles

    1. Pots

    2. Jugs

    3. Common bricks

    4. All of these

    Option 4 – All of these

    Earthenware articles are made from

    1. Common clays

    2. Red clays

    3. Black clays

    4. Brown clays

    Option 2 – Red clays

    Temperature to which Earthenware is subjected to :

    1. 1100°C

    2. 1450-1800°C

    3. 600-900°C

    4. 150°-650°C

    Option 2 – 1450-1800°C

    Oxide of which metal can be found in glazed ceramics?

    1. pb

    2. pd

    3. Ni

    4. Mn

    Option 1 – pb

    Which of the following are not earthenware articles?

    1. pots

    2. common bricks

    3. tiles

    4. spark plugs

    Option 4 – spark plugs

    Plastic contain

    1. Polymeric organic material

    2. Polymeric inorganic material

    3. Soda ash

    4. Metal oxides

    Option 1 – Polymeric organic material

    Polymeric organic substance is commonly known as

    1. Resin

    2. Rexine

    3. Ceramic

    4. None of these

    Option 1 – Resin

    An example for a addition polymer is

    1. Polythene

    2. Poly acrylonitrile

    3. Polyvinyl chloride

    4. All the above

    Option 4 – All the above

    Polypeptides are formed by

    1. Oxidation reaction

    2. Reduction Reaction

    3. Additional Polymerization

    4. Condensation polymerization

    Option 4 – Condensation polymerization

    Polythene is used to make

    1. carry bags

    2. combs

    3. pipes

    4. films

    Option 1 – carry bags

    Polystyrene is used to make

    1. Milk cartons

    2. TV lining

    3. Hand bags

    4. Recording tapes

    Option 2 – TV lining

    Polyvinyl Chloride is used to make

    1. brushes

    2. films

    3. carpets

    4. pipes

    Option 4 – pipes

    Polyesters are used to make

    1. Rain coats

    2. Containers

    3. Films

    4. Gramophone records

    Option 3 – Films

    Nylon 6,6 is used to make

    1. Brushes

    2. Floor coverings

    3. Toys

    4. Electrical insulators

    Option 1 – Brushes

    Material used in carry bags

    1. Polyesters

    2. Nylon 6,6

    3. Low density polyethylene

    4. High density polyethylene

    Option 3 – Low density polyethylene

    Material used in containers

    1. Low density polyethylene

    2. High density polyethylene

    3. Polystyrene

    4. Polyvinyl chloride

    Option 2 – High density polyethylene

    Animal glue made from

    1. Bones of animals

    2. Brain of animals

    3. Liver of animals

    4. Blood of animals

    Option 1 – Bones of animals

    The raw slurry or raw meal is called

    1. Gangue

    2. Raw material

    3. Charge

    4. None of these

    Option 3 – Charge

    The rotary kiln consists

    1. Steel cylinder

    2. Screw conveyer

    3. Burner

    4. Coal

    Option 1 – Steel cylinder

    The length of cylinder in kiln is

    1. 150 metres

    2. 50 metres

    3. 100 metres

    4. 75 metres

    Option 1 – 150 metres

    The diameter of steel cylinder in rotary kiln is

    1. 2 metres

    2. 3 metres

    3. 4 metres

    4. 5 metres

    Option 3 – 4 metres

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