First Law of Thermodynamics MCQ

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    mcq on First Law of Thermodynamics for Students

    CO₂ gas initially at 50 atm and 300 K undergoes an adiabatic free expansion to a volume that is 20 times greater. What is the temperature change?

    a) 3.3°C

    b) 33°C

    c) 0°C

    d) 33 K

    Option b – 33°C

    Entropy increases in a thermodynamic system when it is used to convert:

    a) Heat into work in a cyclic process

    b) Heat into work through a cyclic transformation

    c) work into Heat at constant temperature

    d) work into Heat cyclically

    Option a – Heat into work in a cyclic process

    The combined expression of the first and second laws of Thermodynamics is:

    a) dU = TdS + dQ

    b) dQ = TdS + PdV

    c) TdS = dU – PdV

    d) None of these

    Option a – dU = TdS + dQ

    Which of the following statements about entropy in reversible processes are true? a. Heat absorbed in any reversible path is independent of the path b. Change in entropy during a reversible process does not depend on the path c. Entropy change is path-independent in a reversible system

    a) a and b are correct

    b) b and c are correct

    c) only b is correct

    d) None of these

    Option b – b and c are correct

    For isothermal, isobaric, and reversible processes, the Gibbs free energy G=H−TSG = H – TSG=H−TS:

    a) Varies linearly

    b) Changes non-linearly

    c) Stays constant but not zero

    d) Equals zero

    Option c – Stays constant but not zero

    During a reversible adiabatic process, which property of the system remains unchanged?

    a) Entropy

    b) Temperature

    c) Specific Heat

    d) Enthalpy

    Option a – Entropy

    In Carnot’s cycle, what is the NET change in entropy of the working substance?

    a) It increases

    b) It remains unchanged

    c) It decreases

    d) None of these

    Option b – It remains unchanged

    Under reversible, isothermal, and isobaric conditions, Gibbs function behaves as:

    a) G > 0 and varies with temperature

    b) G stays constant

    c) G < 0 and varies with entropy

    d) G depends on both temperature and entropy

    Option b – G stays constant

    Entropy decreases in a gaseous system when it expands through:

    a) Adiabatic work

    b) Seepage without volume change

    c) Heat-induced work

    d) None of the above

    Option b – Seepage without volume change

    How much mechanical energy is required to melt 1 gram of ice?

    a) 336 J

    b) 80 J

    c) 36 J

    d) 42 J

    Option a – 336 J

    If a blackbody at 1227°C emits energy at a rate E, then at 2727°C, it emits energy at:

    a) 16E

    b) 4E

    c) 2E

    d) 8E

    Option a – 16E

    An ideal gas is heated at constant pressure, doubling its volume. If it started at 27°C, its final temperature is:

    a) 300°C

    b) 600°C

    c) 54°C

    d) 327°C

    Option b – 600°C

    For an ideal gas, the internal energy depends solely on:

    a) Temperature

    b) Pressure

    c) Volume

    d) Size of molecules

    Option a – Temperature

    In a P-V diagram, what does the area under the curve represent?

    a) work done on the system

    b) A thermodynamic process

    c) work in a cyclic process

    d) None of these

    Option a – work done on the system

    At what temperature (in Kelvin) will hydrogen molecules have the same average speed as nitrogen molecules at 35°C?

    a) 495

    b) 22

    c) 275

    d) 42

    Option b – 22

    For an ideal gas undergoing a process where dW=0dW = 0dW=0 and dQ<0dQ < 0dQ<0, what happens?

    a) Temperature decreases

    b) Volume increases

    c) Pressure remains constant

    d) Temperature increases

    Option a – Temperature decreases

    In a pressure-volume diagram, the area enclosed within a closed loop indicates:

    a) Work done in a cyclic process

    b) A thermodynamic change

    c) The state of the system

    d) None of these

    Option a – Work done in a cyclic process

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